n_BaCl2= 0,1 (mol)

n_H2SO4 = 0,2327 (mol)

BaCl₂ + H₂SO₄ \(\rightarrow\) BaSO₄ \(\downarrow\) + 2HCl

bđ 0,1 0,2327 }

pư 0,1 \(\rightarrow\) 0,1 \(\rightarrow\) 0,1 \(\rightarrow\) 0,2 } (mol)

spư 0 0,1327 0,1 0,2 }

m_BaSO4 = 0,1 . 233 = 23,3 (g)

mdd(sau pư)= 400 + 1,14 . 100 - 23,3 =490,7 (g)

C%_(H2SO4)=\(\frac{0,1327.98}{490,7}\) . 100% = 2,65%

C% (HCl) =\(\frac{0,2.36,5}{490,7}\) . 100% = 1,49%

mBaCl2 = 400.5,2% = 20,8g 
mH2SO4 = 100.1,14.20% = 22,8g 

BaCl2 + H2SO4 = BaSO4 + 2HCl 
208...... 98........... 233........ 2.36,5g 
20,8..... 22,8......... 

20,8/208 < 22,8/98 => BaCl2 phản ứng hết và H2SO4 còn dư 
=> mBaSO4 = 20,8.233/208 = 23,3g 
=> mHCl = 20,8.2.36,5/208 = 7,3g 
=> mH2SO4 (dư) = 22,8 - 20,8.98/208 = 13g 

mdd (trước ph.ư) = 400 + 100.1,14 = 514g 
mdd (sau ph.ư) = 514 - 23,3 = 490,7g 

=> C%HCl = 7,3/490,7 = 1,49% 
=> C%H2SO4 (dư) = 13/490,7 = 2,65% 

nbacl2= 400*5,2/(100*208)=0,1 mol

mdd h2so4= 100*1,14=114g

nh2so4=114*20/(100*98)=57/245 mol

bacl2+ h2so4-> baso4+ 2hcl

thấy 0,1< 57/245

=> sau pư bacl2 hết, h2so4 còn dư

nh2so4 dư=57/245-0,1=13/98

n baso4= nbacl2= 0,1 mol

=> mbaso4= 0,1*233=23,3g

mdd sau pư=400+114-23,3=490,7g

C% h2so4 dư=13/98*98*100/490,7=2,65%

C% hcl=0,1*2*36,5*100/490,7=1,49%

a, \(H_2SO_4+BaCl_2\rightarrow BaSO_{4\downarrow}+2HCl\)

b, Ta có: \(m_{H_2SO_4}=114.20\%=22,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{22,8}{96}=0,2375\left(mol\right)\)

\(m_{BaCl_2}=400.5,2\%=20,8\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{20,8}{208}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2375}{1}>\dfrac{0,1}{1}\), ta được H₂SO₄ dư.

Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,1\left(mol\right)\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{BaCl_2}=0,1\left(mol\right)\\n_{HCl}=2n_{BaCl_2}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2375-0,1=0,1375\left(mol\right)\)

Ta có: m _{dd sau pư} = 114 + 400 - 23,3 = 490,7 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,1375.98}{490,7}.100\%\approx2,75\%\\C\%_{HCl}=\dfrac{0,2.36,5}{490,7}.100\%\approx1,49\%\end{matrix}\right.\)

Theo đề bài ta có :

\(\left\{{}\begin{matrix}nH2SO4=\dfrac{\left(100.1,14\right).20}{98.100}\approx0,23\left(mol\right)\\nBaCl2=\dfrac{400.5,2}{100.208}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có PTHH :

\(BaCl2+H2SO4->B\text{aS}O4\downarrow+2HCl\)

0,1mol.......0,1mol.............0,1mol.......0,2mol

Theo PTHH ta có : \(nBaCl2=\dfrac{0,1}{1}mol< nH2SO4=\dfrac{0,23}{1}mol\)

=> nH2SO4 dư ( tính theo nBaCl2)

a) Ta có : mBaSO4 = 0,1.233=23,3(g)

b) Ta có : \(\left\{{}\begin{matrix}C\%H2SO4\left(d\text{ư}\right)=\dfrac{\left(0,23-0,1\right).98}{100.1,14+400-23,3}.100\%\approx2,596\%\\C\%HCl=\dfrac{0,2.36,5}{100.1,14+400-23,3}.100\%\approx1,49\%\end{matrix}\right.\)

Vậy.......

a) mBaCl₂ = 20,8 g => nBaCl₂ = 0,1 mol

mH₂SO₄ = \(\frac{m_{dd}C\%}{100}\) = \(\frac{100.1,14.20}{100}\) = 22,8 g => nH₂SO₄ ≃ 0,2 mol

BaCl₂ + H₂SO₄➝ BaSO₄↓ + 2HCl

bđ: 0,1 0,2

pứ: 0,1 0,1

dư: 0 0,1

Vậy BaCl₂ hết, H₂SO₄ dư, bài toán tính theo BaCl₂

nBaSO₄ = nBaCl₂ = 0,1 mol

=> mBaSO₄ = 23,3 g

b) nHCl = 2nBaCl₂ = 0,1 mol

=> C_M = 1 M

nH₂SO_4dư = 0,1 mol => C_M = 1 M

\(n_{H_2SO_4}=\dfrac{100.1,14.20\%}{98}=0,233\left(mol\right)\)

\(n_{BaCl_2}=\dfrac{5,2\%.400}{108}=0,1\left(mol\right)\)

\(H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\)

0,233..........0,1

Lập tỉ lệ : \(\dfrac{0,233}{1}>\dfrac{0,1}{1}\) => H2SO4 dư

\(m_{BaSO_4}=0,1.233=23,3\left(g\right)\)